The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Peroxy radicals / Alkylperoxy / C2H5O2 / Bauer(1992)_298K_215-295nm

DATAFILE: C2H5O2_Bauer(1992)_298K_215-295nm.txt
NAME: ethylperoxy radical
FORMULA: C2H5O2
AUTHOR(YEAR): Bauer(1992)
T: 298K
λ: 215-295nm
BIBLIOGRAPHY: D. Bauer, J.N. Crowley, and G.K. Moortgat, "The UV absorption spectrum of the ethylperoxy radical and its self-reaction kinetics between 218 and 333 K", J. Photochem. Photobiol. A: Chem. 65, 329-344 (1992); DOI: 10.1016/1010-6030(92)80015-N
COMMENTS: Absorption measurements using the molecular modulation technique (modulated photolysis of flowing Cl2/C2H6/O2/N2 mixtures) in conjunction with both single wavelength and diode array UV spectroscopy; spectral resolution better than 0.5 nm

The cross-sections were measured relative to HO2 and have been corrected to a new recommendation for σ(HO2) of

P- D. Lightfoot, R. A. Cox, J. N. Crowley, M. Destriau, G. D. Hayman, M. E. Jenkin, G. K. Moortgat, and F. Zabel, "Organic peroxy radicals: Kinetics, spectroscopy and tropospheric chemistry", Atmos. Environ., 26A, 1805-1961 (1992); DOI: 10.1016/0960-1686(92)90423-I

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